ON MECHANISM OF OXYGEN PARTICIPATION IN OXIDING AMMONOLYSIS OF 4-PHENOXYTOLUENE ON OXIDE CATALYSTS

Using the impulse method, researchers explored a separate interaction of toluene and ammonia with a surface of oxide Bi-V-Sb-Cr-K-catalyst in the reaction of oxidizing ammonolysis 4-phenoxitoluol. Results of the research showed that the formation of 4-phenoxibenzonitryl occurs according to the oxidizing-restoration mechanism. Products of deep oxidation of 4-phenoxitoluene are formed due to oxidizing-restoration and associative mechanism.
Keywords:oxidizing ammonolysis, 4-phenoxytoluene, 4-phenoxybenzonytril, oxide catalysts.