COMPLEX COMPOUNDS OF PALLADIUM (II) WITH γ – GLUTAMIC ACID AMIDE

Kh.I. Gasanov, A.N. Azizova, N.M. Kuliyeva, Sh.G. Gasimov

Abstract

This study examined the formation of palladium (II) complex compounds with γ-glutamic acid amide in aqueous solutions and calculated the complex stability constants, also known as formation constants. After the complexes were separated from one another, each compound's structure and characteristics were studied individually. Based on data from NMR, IR, and UV spectroscopy it was established, that two ligand molecules coordinate in a monodentate manner along the donor nitrogen atoms of the amino group and in a bidentate manner along the nitrogen atoms of the amino group and oxygen. A planar square internal coordination sphere is formed in the trans- structure, respectively, in the complexes [Pd2Namine2Cl] ([PdL2Cl2]), [Pd2Namine2Ocarb] ([Pd(НL)2]).

https://doi.org/10.32737/2221-8688-2024-3-342-349

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