CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF 4-{2,2-DICHLORO-1-[(E)-(2,4-DICHLOROPHENYL)DIAZENYL]ETHENYL}-N,N-DIMETHYLANILINE

A.M. Maharramov, U.F. Askerova, N.E. Ahmedova, A.B. Askarov, D.B. Tagiyev, Sh.I. Gahramanova, I.M. Shikhaliyeva, S.H. Mukhtarova, M. Akkurt

Abstract

In the title compound, C16H13Cl4N3, the dihedral angle between the benzene rings of the dichlorophenyl and dimethylaniline groups is 50.85 (13)°. The central –N=N– unit shows an E configuration. In the crystal, molecules form parallel layers to the (100) plane by C—H···π and face-to-face π-π [centroid-to-centroid distances = 4.0538 (17) and 4.0537 (17) Å] interactions. These layers are connected by Van der Waals interactions to stabilize the crystal structure. Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from Cl···H/H···Cl (36.4%), H···H (23.3%) and C···H/H···C (15.2%) contacts.

https://doi.org/10.32737/2221-8688-2024-4-499-508