The polymerization of copper (II) salt of acryl and 2-ethoxycarbonylcyclopropane carboxylic acids initiated by electrical current on graphite electrodes in aqueous solution of dioxane at current density 0.01-0,1 A/cm2 has been studied, optimal conditions of electrolysis identified
and an influence of current density and quantity of electricity on yield of polymer studied. It has been established that the finished polymer is photo-sensitive and thermo stable.