MULTI-3D MODELING OF PHASE DIAGRAM OF PbTe-Bi2Te3-Sb2Te3 SYSTEM

A.I. Aghazade, S.M. Rustamova, I.M. Gojayeva, E.N. Orujlu, D.M. Babanly, A.N. Mammadov

Abstract

Using the analytical option of the Origin Lab computer program, the analytical dependences of the liquidus temperature on the composition for the PbTe-Bi2Te3, PbTe-Sb2Te3, Bi2Te3-Sb2Te3 boundary systems of the PbTe-Bi2Te3-Sb2Te3 ternary system were determined. Based on these dependencies and thermal analysis data of the ternary system, the analytical model of the temperature-composite dependence of the crystallization surfaces of PbTe, Sb2Te3, Bi2Te3 compounds and PbBi2Te4, PbBi4Te7, PbBi6Te10 phases in the PbTe-Bi2Te3-Sb2Te3 system was determined. The resulting equations made it possible to visualize the phase diagram of the PbTe-Bi2Te3-Sb2Te3 system from the side of the PbTe-Bi2Te3 in 3D coordinates. The analytical model of the phase diagram of the PbTe-Bi2Te3-Sb2Te3 system allowed constructing a three- dimensional image of equilibrium phases from different angles, to obtain two-dimensional projections and to tabulate the coordinates of the phase diagram.

https://doi.org/10.32737/2221-8688-2023-4-353-360