Phase equilibriums in the Tl5Te3-Tl4PbTe3-Tl9BiTe6 (A) system were investigated using DTA, EMF, X-ray methods and measurement of microhardness. Three ray polythermal sections as Tl5Te3-Tl8+х+yPbуBiхTe6 type, projection of liquidus and solidus surfaces of the system (A) and graphics of dependence of microhardness, EMF and parameters of crystalllatice on concentration were constructed. It was established that the system (A) is characterized by formation of non-limited solid solutions with tetragonal structure as Tl5Te3 type.