Using interaction of R-β-γ-dichlor-1-propenylketones with 4-aminopyridine, the previously unknown corresponding hydrochloric acid salts of β-(4’aminopyridyl)-γ-chlor-1-propenylketones have been obtained. Processed by saturated aqueous solution of potassium carbonate these compounds have been converted into R-β-(4’aminopyridyl)-γ-chlor-1-propenylketones. The structures of the synthesized compounds have been confirmed by IR-, NMR 1H- and UV-spectroscopy.