Sulphide and also azo, sulphurcontaining new organic compounds on replacement of chlorine atom 1-methyl-1-clorine-2-oktoxymethil-cyclohexane to atoms sulphur and nitrogen has been obtained. Synthesed new organic compounds have been investigated as inhibitors of steel metals from corrosion in high aggressive medium. It has been established that with increase of atom nitrogen in organic compounds and functional groups as well effectivity of inhibitors increases.