On the basis of ethers of α-chlorine-alkoxymethyl (oktoxymethyl, desoxymethyl, undesoxymethyl) 12 new and previously unknown nitrogenbearning organic compounds have been obtained and their inhibitory properties studied. The experiments showed that the most effective (96-100%) inhibitors of corrosion out of synthesized compounds are the ones with a greater number of nitrogen atoms and CH2-groups.