Abstract: The reactions of mercaptoacetic acid esters with enamines, specifically with 1-morpholino- and 1-piperidino-1-cycloalkenes, have been studied. It was established that the reactions proceed readily in the absence of a catalyst, yielding 1-morpholino- and 1-piperidino-1-alkoxycarbonylmethylthio-cycloalkanes. The composition and structure of the obtained aminosulfides were confirmed by IR and NMR (1H and 13C) spectroscopy, as well as by elemental analysis.
Chemical Problems; 2026; V. 24(2); p. 296-301
SYNTHESIS OF 1-MORPHOLINO- AND 1-PIPERIDINO-1-ALKOXY-CARBONYLMETHYLTHIOCYCLOALKANES
Institute of Chemistry of Additives named after academician A.M.Guliyev of the Ministry of Science and Education Republic of Azerbaijan
E-mail:
*leylavahidzade98@gmail.com
Received Date: 2025-07-15
Accepted Date: 2025-09-23