The phase microdiagram of the (Sb2Te3+Bi2Te3+Se+Te)1-х(Pr)х system has been studied using differential thermal analysis, X-ray diffraction, microstructural analysis, and microhardness and density measurements. The influence of Pr element on physico-chemical properties of solid solution (Sb2Te3+Bi2Te3+Se+Te) of “p”-type analysed. At room temperature, the
(Sb2Te3+Bi2Te3+Se+Te) based solid solution extends to 4 at. % Pr