WATER-DILUTING EPOXIDE TELOMER BASED ON DIBUTYL ETHER OF ADIPINIC ACID

A.Z. Chalabiyeva, N.Ya. Ishenko, D.R. Nurullayeva, B.A. Mamedov

Abstract

A water-diluting epoxidetelomer was synthesized on the basis of allylglycidyl ether and dibutyl ether of adipinic acid under the effect of free radicals being generated during thermal decay of ditretbutyl peroxide. The reaction proceeds in one stage, the process is wasteless and fire-safe while the unreacted allylglycidyl ether returns to the reaction. The synthesized epoxytelomer is a low-viscous resin of light- yellow color, soluble in water, chloroform, acetone, M.w.=380-400 g.mol-1, epoxide number –18-19%. The composition and structure of the obtained telomer were established due to physical and chemical investigations. The composition materials of hot and cold curing were developed on the basis of the obtained telomer. The curing process was studied by a method of differential-thermal analysis to show that the obtained materials were characterized by high heat-resistance and thermal stability. It revealed that the epoxide telomer has surface-active properties.

https://doi.org/10.32737/2221-8688-2020-4-451-456

Article metrics

1Views
0PDF downloads

Measured on this website since 2026-10-08. Repeat events in the same browser within one hour are counted once. PDF counts record clicks from this article page, not confirmed completed downloads.

External attention metrics are supplied by their providers and may be unavailable for this DOI. They are not a measure of research quality.